(Pentamethylcyclopentadienyl)titanium trichloride

(Pentamethylcyclopentadienyl)­titanium trichloride
Names
Other names
Cp*TiCl3
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.152.688 Edit this at Wikidata
UN number 3261
  • InChI=1S/C10H15.3ClH.Ti/c1-6-7(2)9(4)10(5)8(6)3;;;;/h1-5H3;3*1H;/q;;;;+3/p-3
    Key: QCEOZLISXJGWSW-UHFFFAOYSA-K
  • CC1=C([C](C(=C1C)C)C)C.Cl[Ti](Cl)Cl
Properties
C10H15Cl3Ti
Molar mass 289.45 g·mol−1
Appearance Orange solid
Melting point 225 °C (437 °F; 498 K)
Hazards
GHS labelling:
GHS05: Corrosive
Danger
H314
P280, P305+P351+P338, P310
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

(Pentamethylcyclopentadienyl)titanium trichloride is an organotitanium compound with the formula Cp*TiCl3 (Cp* = C5(CH3)5). It is an orange solid. The compound adopts a piano stool geometry. An early synthesis involve the combination of lithium pentamethylcyclopentadienide and titanium tetrachloride.

The compound is an intermediate in the synthesis of decamethyltitanocene dichloride. In the presence of organoaluminium compounds and other additives, it catalyzes the polymerization of alkenes.

See also


This page was last updated at 2023-10-21 19:15 UTC. Update now. View original page.

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