Thorite

Thorite
Thorite crystal from the Kemp uranium mine in Ontario (size: 2.2 x 2.2 x 1.6 cm)
General
CategorySilicate mineral
Formula
(repeating unit)
(Th,U)SiO4
IMA symbolThr
Strunz classification9.AD.30
Crystal systemTetragonal
Crystal classDitetragonal dipyramidal (4/mmm)
H-M symbol: (4/m 2/m 2/m)
Space groupI41/amd
Unit cella = 7.13, c = 6.32 [Å]; Z = 4
Identification
ColorYellow-orange, brownish yellow, brownish black, black, green
Crystal habitIn square prisms, or pseudo-octahedral crystals; also massive
CleavageDistinct on {110}
FractureConchoidal
TenacityBrittle
Mohs scale hardness4.5 – 5
LusterVitreous to resinous
StreakLight orange to light brown sometimes even an alien magenta
DiaphaneityNearly opaque, transparent in thin fragments
Specific gravity6.63 – 7.20
Optical propertiesUniaxial (−)
Refractive indexnω = 1.790 – 1.840 nε = 1.780 – 1.820
Birefringenceδ = 0.010 – 0.020
Alters toCommonly metamict
Other characteristics Radioactive
References

Thorite, (Th,U)SiO4, is a rare nesosilicate of thorium that crystallizes in the tetragonal system and is isomorphous with zircon and hafnon. It is the most common mineral of thorium and is nearly always strongly radioactive. Thorite was discovered in 1828 on the island of Løvøya, Norway, by the vicar and mineralogist, Hans Morten Thrane Esmark. First specimens of Thorite were sent to his father, Jens Esmark, who was a professor of mineralogy and geology. It was named in 1829 to reflect its thorium content.

Occurrence

Thorite in Prague national museum
Small crystals of green thorite under magnification

Specimens of thorite generally come from igneous pegmatites and volcanic extrusive rocks, hydrothermal veins and contact metamorphic rocks. It is also known to occur as small grains in detrital sands. Crystals are rare, but when found can produce nicely shaped short prismatic crystals with pyramidal terminations. It is commonly associated with zircon, monazite, gadolinite, fergusonite, uraninite, yttrialite and pyrochlore.

Thorite is currently an important ore of uranium. A variety of thorite, often called "uranothorite", is particularly rich in uranium and has been a viable uranium ore at Bancroft in Ontario, Canada. Other varieties of thorite include "orangite", an orange variety, and "calciothorite", an impure variety with trace amounts of calcium.

Properties

Due to the radioactive elements contained, Thorite is commonly metamict. With the destructive effects of radioactivity on the crystal lattice, hydrated specimens are often amorphous and optically isotropic. Owing to differences in composition, the specific gravity varies from 4.4 to 6.6 g/cm3. Hardness is 4.5 and the luster is vitreous or resinous. The color is normally black, but can range from brownish black to orange, yellowish-orange and dark green.


This page was last updated at 2024-01-19 12:47 UTC. Update now. View original page.

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