Titanyl sulfate

Titanyl sulfate
Identifiers
3D model (JSmol)
ChemSpider
ECHA InfoCard 100.034.098 Edit this at Wikidata
UNII
  • [O-]S(=O)(=O)[O-].O=[Ti+2]
Properties
O5STi
Molar mass 159.92 g·mol−1
Density 1.3984 g/cm3
Except where otherwise noted, data are given for materials in their standard state (at 25 °C [77 °F], 100 kPa).
Infobox references

Titanyl sulfate is the inorganic compound with the formula TiOSO4. It is a white solid that forms by treatment of titanium dioxide with fuming sulfuric acid. It hydrolyzes to a gel of hydrated titanium dioxide. The structure consists of dense polymeric network with tetrahedral sulfur and octahedral titanium centers. The six ligands attached to titanium are derived from four different sulfate moieties and a bridging oxide. A monohydrate is also known, being prepared similarly to the anhydrous material. In the hydrate, one Ti–OS bond is replaced by Ti–OH2.

Portions of the structure of titanyl sulfate
TiOSO4, illustrating the connectivity between sulfate and titanium centers
TiOSO4(H2O), showing the presence of water
Color code: Ti = blue, O = red, and S = yellow



This page was last updated at 2023-08-15 02:41 UTC. Update now. View original page.

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